An efficient extraction and clean‐up procedure for pesticide determination in olive oil

This work reports a simple, rapid, and effective extraction method based on liquid–liquid extraction (LLE) followed by matrix solid‐phase dispersion‐sonication for detection, identification and quantification of multiclass pesticides in virgin olive oil using liquid chromatography mass spectrometry (LC‐QTOF‐MS). LLE to extract pesticide residues in virgin olive oil was performed in order to study the centrifugation efficiency to obtain high recovery yield and low co‐extract fat residue in the final extract. Different suitable parameters of MSPD procedure were evaluated, such as nature of dispersing phase, clean‐up adsorbent, and volume of eluting solvent (acetonitrile) in different extraction conditions, with or without sonication. The best results were obtained using 5 g of virgin olive oil, 2 g of PSA as dispersant sorbent, 2 g of Florisil/GCB (70:30 w/w) as clean‐up sorbent, and 15 mL of acetonitrile as eluting solvent under conditions of 15 min ultrasonic bath at RT. Method validation was performed in order to study sensitivity, linearity, precision, and accuracy. Average recoveries ranged between 73.7 and 104.2% with relative SDs 5.3–13.4% at three concentration levels (25, 50, and 100 µg/kg). Detection and quantification limits ranged from 1.5 to 5 µg/kg and 3 to 9 µg/kg, respectively.     

Physicochemical and sensory characteristics of no‐bake wheat–soy snack bars

BACKGROUND: Health and wellness is a trend observed throughout ready‐to‐eat cereals, cereal health bars. Therefore, the main objectives of this research were to produce a low cost, acceptable, nutritious and healthy wheat‐ and soy‐based bar under no‐bake conditions. Also, the physical, chemical, microbial, acceptability and the nutritional value of this product were studied. Six different bars were produced: a wheat bar (WB), a wheat bar with coating (WBC), a wheat and soy bar with coating (WSBC), a soy bar with coating (SBC), a wheat bar with 3% glycerin (WB3%), and a wheat bar with 6% glycerine (WB6%). RESULTS: WB and WBC had the highest water activities while WSBC had the lowest. The three bars with coating had higher L and lower b values, which indicates that they were lighter and not as highly yellow coloured as the wheat samples. WSBC had the lowest value for hardness while the SBC and WBC had the highest. SBC received the highest scores for overall acceptability, appearance, sweetness, flavour and texture while WSBC received the second highest score in all categories. CONCLUSION: It appears that consumers prefer the soy varieties to the wheat bars. These types of bars can aid in feeding the general population, which is becoming increasingly concerned with nutrition and convenience. Copyright © 2010 Society of Chemical Industry     

Copolymerization of carbon monoxide with exo‐methylenecycloalkane and dienes: synthesis of functionalized aliphatic polyketones

Synthesis of functional aliphatic polyketones was achieved by co‐ and terpolymerization of the strained exo‐methylenecycloalkane, methylenecyclopropane (MCP), and also the dienes 1,5‐hexadiene, 1,7‐octadiene and 1,6‐heptadien‐4‐ol, with carbon monoxide and propene, using the dicationic palladium(II) phosphine complex [Pd(dppp) (NCCH₃)₂](BF₄)₂ (I) (dppp is 1,3‐bis(diphenyl‐phosphino)propane) as the catalyst precursor. The resulting MCP/CO copolymer contains both ring‐opened and cyclic microstructures. Ring‐opening copolymerization yields exo‐methylene functionalized polyketone. In contrast to hexadiene/carbon monoxide copolymer (Hx/CO), no ring structures were observed in the alternating octadiene/carbon monoxide (Oc/CO) and heptadien‐4‐ol/carbon monoxide (Hp‐ol/CO) copolymers. The remaining double bonds were left intact to yield polymers with olefinic functionalities in the side chains. © 2001 Society of Chemical Industry     

Origin of Surface Irregularities on Ti–10V–2Fe–3Al Beta Titanium Alloy

We studied the origin of different characteristics and properties of a Ti–10V–2Fe–3Al beta (β) titanium alloy with surface height irregularities that occurred during machining. The height differences were observed in two different regions, labeled as “soft region” and “hard region.” The present study showed a higher Fe and a lower Al content in the hard region, which resulted in higher β-phase stability to resist primary alpha (α_p) phase precipitation caused by a failure of the solution treatment process. In contrast, the soft region contained a higher volume fraction of α_p phase and a lower volume fraction of the matrix, which consisted of a combination of β and secondary alpha (α_s) phase. A high number of α_s/β interface in the matrix with a predicted hardness of 520 HV generated an improvement of hardness in the hard region. Therefore, the hard and the soft regions had different abilities to resist wear during machining process, resulting in surface height irregularities.     

Effect of Postweld Heat Treatment on Microstructure, Hardness, and Tensile Properties of Laser-Welded Ti-6Al-4V

The effects of postweld heat treatment (PWHT) on 3.2-mm- and 5.1-mm-thick Ti-6Al-4V butt joints welded using a continuous wave (CW) 4-kW Nd:YAG laser welding machine were investigated in terms of microstructural transformations, welding defects, and hardness, as well as global and local tensile properties. Two postweld heat treatments, i.e., stress-relief annealing (SRA) and solution heat treatment followed by aging (STA), were performed and the weld qualities were compared with the as-welded condition. A digital image correlation technique was used to determine the global tensile behavior for the transverse welding samples. The local tensile properties including yield strength and maximum strain were determined, for the first time, for the laser-welded Ti-6Al-4V. The mechanical properties, including hardness and the global and local tensile properties, were correlated to the microstructure and defects in the as-welded, SRA, and STA conditions.     

A review of investigations on liquid fuel combustion in porous inert media

Utilization of a porous medium for combustion of liquid fuels is proved to be a promising approach for future applications. The porous medium burner for liquid fuels is more advantageous than the conventional open spray flame burner for several reasons; these include enhanced evaporation of droplet spray owing to regenerative combustion characteristics, low emission of pollutants, high combustion intensity with moderate turn-down ratio and compactness. This article provides a comprehensive picture of the global scenario of research and developments in combustion of liquid fuels within a porous medium that enable a researcher to determine the direction of further investigation. Accordingly, a glossary of the important terminology, the modeling approach, advances in numerical and experimental works and applications are included. The papers published in standard journals are reviewed and summarized with relevant comments and suggestions for future work.     

Effects of radiation process on total protein and amino acids composition of raw and processed pearl millet flour during storage

The present work describes radiation‐induced effects during storage on total protein and amino acids composition of raw and processed flour of two pearl millet cultivars (Ashana and Dembi). The protein content of the whole raw flour was 14.46% and 13.38% for Ashana and Dembi cultivars, respectively. Dehulling of the grains reduced the protein content to 13.38% and 12.67% for the cultivars, respectively. Storage of the radiated whole and dehulled flour for 60 days slightly reduced the protein content even after cooking. The effect of radiation process in combination with the treatments applied to the grains and/or flour on amino acids contents was found to be varying between the cultivars. Most of the amino acids were stable against all treatments except leucine, glutamic acid and phenylalanine. Regardless of the storage period and processing method, amino acid contents of Ashana cultivar were increased after radiation process compared to that of Dembi cultivar.     

Optimized Reliable Hybrid Routing Protocol Based Link Stability for Mobile Wireless Networks

Wireless Personal Communications - During the last two decades, there has been a tremendous growth in the use of MANETs, not only due to the development of the technology but also due to their high...     

Cache modeling and optimization for portable devices running MPEG-4 video decoder

There are increasing demands on portable communication devices to run multimedia applications. ISO (an International Organization for Standardization) standard MPEG-4 is an important and demanding multimedia application. To satisfy the growing consumer demands, more functions are added to support MPEG-4 video applications. With improved CPU speed, memory sub-system deficiency is the major barrier to improving the system performance. Studies show that there is sufficient reuse of values for caching that significantly reduce the memory bandwidth requirement for video data. Software decoding of MPEG-4 video data generates much more cache-memory traffic than required. Proper understanding of the decoding algorithm and the composition of its data set is obvious to improve the performance of such a system. The focus of this paper is cache modeling and optimization for portable communication devices running MPEG-4 video decoding algorithm. The architecture we simulate includes a digital signal processor (DSP) for running the MPEG-4 decoding algorithm and a memory system with two levels of caches. We use VisualSim and Cachegrind simulation tools to optimize cache sizes, levels of associativity, and cache levels for a portable device decoding MPEG-4 video. Abu Asaduzzaman is, currently, a PhD candidate in the department of Computer Science and Engineering (CSE), Florida Atlantic University (FAU), Boca Raton, Florida. He received his MS degree in computer engineering from FAU in 1997. Mr. Asaduzzaman worked for ECI Telecom as a software engineer from 1998 to 2001. From 2001 to 2003, he worked for BlueCross and BlueShield of Florida and SunPass (FDoT) as an IT Consultant. Currently, he is working as a research assistant at CSE Dept, FAU. His research interests include cache optimization, architecture exploration, embedded system evaluation, and networks-on-a-chip (NoC). He has published several research papers in these areas. Abu is a member of the honor society of Phi Kappa Phi, Tau Beta Pi, Upsilon Phi Epsilon, and the Association for Computing Machinery (ACM) FAU Chapter. Imad Mahgoub received the MS degree in applied mathematics and MS degree in electrical and computer engineering, both from North Carolina State University, Raleigh in 1983 and 1986 respectively and the PhD degree in computer engineering from the Pennsylvania State University, University Park, PA in 1989. Dr. Mahgoub joined Florida Atlantic University (FAU), Boca Raton, Florida in 1989. Currently he is a full professor of Computer Science and Engineering department and the director of the Mobile Computing Laboratory. His research interests include performance evaluation, mobile computing, sensor networks, and parallel and distributed processing. He has published over 80 research papers in these areas. He is the co-editor of the Mobile Computing Handbook and the Handbook of Sensor Networks. Dr. Mahgoub has served on the program committees of numerous conferences. He has been the vice-chair for the Symposium on Performance Evaluation of Computer and Telecommunication Systems (SPECTS) since 2003. He is a senior member of the IEEE. He is also a member of Tau Beta Pi, Upsilon Pi Epsilon, the IEEE Computer Society, and the ACM.     

Distribution of sulphate reducing bacteria in oil emulsion and its relationship to aeration and swarf

Intermittent aeration of cutting oil emulsion was shown to reduce but not eliminate sulphate reducing bacteria (srb). Removing iron swarf from infected cutting fluid markedly reduced the numbers of srb detected in the fluid, and prevented the characteristic grey spoilage which these organisms promote. It was shown that large numbers of srb are in fact adherent to the metal surfaces.